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Prof. Dr. Peter Hess 《Chemphyschem》2022,23(6):e202100880
In the periodic table the position of each atom follows the ‘aufbau’ principle of the individual electron shells. The resulting intrinsic periodicity of atomic properties determines the overall behavior of atoms in two-dimensional (2D) bonding and structure formation. Insight into the type and strength of bonding is the key in the discovery of innovative 2D materials. The primary features of 2D bonding and the ensuing monolayer structures of the main-group II–VI elements result from the number of valence electrons and the change of atom size, which determine the type of hybridization. The results reveal the tight connection between strength of bonding and bond length in 2D networks. The predictive power of the periodic table reveals general rules of bonding, the bonding-structure relationship, and allows an assessment of published data of 2D materials. 相似文献
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Study on divertor plasma behavior through sweeping strike point in new lower divertor on EAST 下载免费PDF全文
Yu-Qiang Tao 《中国物理 B》2022,31(6):65204-065204
A series of L-mode discharges have been conducted in the new ‘corner slot’ divertor on the Experimental Advanced Superconducting Tokamak (EAST) to study the divertor plasma behavior through sweeping strike point. The plasma control system controls the strike point sweeping from the horizontal target to the vertical target through poloidal field coils, with keeping the main plasma stability. The surface temperature of the divertor target cools down as the strike point moves away, indicating that sweeping strike point mitigates the heat load. To avoid the negative effect of probe tip damage, a method based on sweeping strike point is used to get the normalized profile and study the decay length of particle and heat flux on the divertor target λjs, λq. In the discharges with high radio-frequency (RF) heating power, electron temperature Te is lower and λjs is larger when the strike point locates on the horizontal target compared to the vertical target, probably due to the corner effect. In the Ohmic discharges, λjs, λq are much larger compared to the discharges with high RF heating power, which may be attributed to lower edge Te. 相似文献
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Jialong Duan Yudi Wang Xiya Yang Qunwei Tang 《Angewandte Chemie (International ed. in English)》2020,59(11):4391-4395
Improved charge extraction and wide spectral absorption promote power conversion efficiency of perovskite solar cells (PSCs). The state‐of‐the‐art carbon‐based CsPbBr3 PSCs have an inferior power output capacity because of the large optical band gap of the perovskite film and the high energy barrier at perovskite/carbon interface. Herein, we use alkyl‐chain regulated quantum dots as hole‐conductors to reduce charge recombination. By precisely controlling alkyl‐chain length of ligands, a balance between the surface dipole induced charge coulomb repulsive force and quantum tunneling distance is achieved to maximize charge extraction. A fluorescent carbon electrode is used as a cathode to harvest the unabsorbed incident light and to emit fluorescent light at 516 nm for re‐absorption by the perovskite film. The optimized PSC free of encapsulation achieves a maximum power conversion efficiency up to 10.85 % with nearly unchanged photovoltaic performances under 80 %RH, 80 °C, or light irradiation in air. 相似文献
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An exceptional n-cycle in a Hom-finite triangulated category with Serre functor has been recently introduced by Broomhead,Pauksztello and Ploog.When n=1,it is a spherical object.We explicitly determine all the exceptional cycles in the bounded derived category D^b(kQ)of a finite quiver Q without oriented cycles.In particular,if Q is an Euclidean quiver,then the length type of exceptional cycles in D^b(kQ)is exactly the tubular type of Q;if Q is a Dynkin quiver of type E_m(m=6,7,8),or Q is a wild quiver,then there are no exceptional cycles in D^b(kQ);and if Q is a Dynkin quiver of type An or D_n,then the length of an exceptional cycle in D^b(kQ)is either h or h/2,where h is the Coxeter number of Q. 相似文献
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Renny Mathew Karolina A. Uchman Lydia Gkoura Chris J. Pickard Maria Baias 《Magnetic resonance in chemistry : MRC》2020,58(11):1018-1025
A combined experimental and computational approach was used to distinguish between different polymorphs of the pharmaceutical drug aspirin. This method involves the use of ab initio random structure searching (AIRSS), a density functional theory (DFT)-based crystal structure prediction method for the high-accuracy prediction of polymorphic structures, with DFT calculations of nuclear magnetic resonance (NMR) parameters and solid-state NMR experiments at natural abundance. AIRSS was used to predict the crystal structures of form-I and form-II of aspirin. The root-mean-square deviation between experimental and calculated 1H chemical shifts was used to identify form-I as the polymorph present in the experimental sample, the selection being successful despite the large similarities between the molecular environments in the crystals of the two polymorphs. 相似文献
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Wenqing Zhang Dr. Jiuxing Li Prof. Dr. Bruno Salena Prof. Dr. Yingfu Li 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(3):592-596
DNA detection is usually conducted under nondenaturing conditions to favor the formation of Watson–Crick base-paring interactions. However, although such a setting is excellent for distinguishing a single-nucleotide polymorphism (SNP) within short DNA sequences (15–25 nucleotides), it does not offer a good solution to SNP detection within much longer sequences. Here we report on a new detection method capable of detecting SNP in a DNA sequence containing 35–90 nucleotides. This is achieved through incorporating into the recognition DNA sequence a previously discovered DNA molecule that forms a stable G-quadruplex in the presence of 7 molar urea, a known condition for denaturing DNA structures. The systems are configured to produce both colorimetric and fluorescent signals upon target binding. 相似文献
10.
AlGaN/GaN HEMT外部边缘电容Cofd是由栅极垂直侧壁与二维电子气水平壁之间的电场构成的等效电容.本文基于保角映射法对Cofd进行物理建模,考虑沟道长度调制效应,研究外部偏置、阈值电压漂移和温度变化对Cofd的影响:随着漏源偏压从零开始增加,Cofd先保持不变再开始衰减,其衰减速率随栅源偏压的增加而减缓;AlGaN势垒层中施主杂质浓度的减小和Al组分的减小都可引起阈值电压的正向漂移,正向阈值漂移会加强沟道长度调制效应对Cofd的影响,导致Cofd呈线性衰减.在大漏极偏压工作情况下,Cofd对器件工作温度的变化更加敏感. 相似文献